- Education
- B.Sc. Addis Ababa University, Addis Ababa, Ethiopia
- Ph.D. Inorganic Chemistry, University of Maine, Orono, ME 1992
- Experience
- 2005-present Associate Professor, Inorganic Chemistry, North Carolina A& T State University
- 1997-2005 Research Staff Scientist, Oak Ridge National Laboratory, TN
- 1995-97 Research Associate III, Oak Ridge National Lab, Oak Ridge, TN
- 1994-95 Research Associate, Auburn University, Auburn, AL
- 1992-94 Post-Doctoral Research Associate, Texas A&M University, TX
- Research Interests
- Coordination and spectroscopy of late-early binuclear transition metal complexes
- Current Projects
(1) Basic research in synthesis, photochemistry and spectroscopy of lanthanide and actinide systems in solids and solutions, and doped in various matrices including in pyrochlores, sol-gel, and borosilicate glasses. (2) Sensitized emission in lanthanide/actinide systems in zirconia, sol-gel, and borosilicate glass matrices. (3) Excited-state energy-transfer, luminescence, and time rresolved spectroscopy. (4)Complexation and energy transfer studies in oxo- and N-ligating benzimidazole based multidentate ligands in solution and solid state.
Selected Publications
(1) Richard E. Sykora, Zerihun Assefa, Thomas E. Albrecht-Schmitt, and Richard G. Haire .The First Structural Determination of a Trivalent Californium Compound with Oxygen Coordination. Inorg. Chem., 2005, in Press.
2) Richard E. Sykora, Zerihun Assefa, Thomas E. Albrecht-Schmitt, and Richard G. Haire .Hydrothermal Synthesis, Structure, and Raman and Emission Spectroscopes of Americium Iodate, 243Am(IO3)3. Inorg. Chem., 2005, 44 (16): 5667-5676.
3) Z. Assefa, T. Yaita , R. G. Haire , S. Tachimori, .Intramolecular energy transfer in actinide complexes of 6-methyl-2-(2-pyridyl)-benzimidazole (biz): Comparison between Cm(III) and Tb(III) systems.. J. Solid State Chem., 178, 2005, 505-510.
4) Richard E. Sykora, Zerihun Assefa, and Richard G. Haire, Thomas E. Albrecht-Schmitt .Hydrothermal Synthesis, Structure, Raman Spectroscopy, and Self-Irradiation Studies of 248Cm(IO3)3. J. Solid State Chem., 177, 2004, 4413 . 4419.
5) Z. Assefa, R. G. Haire, D. L. Caulder, D. K. Shuh, .Correlation of the oxidation state of cerium in sol-gel glasses as a function of thermal treatment via optical spectroscopy and XANES studies.. Spectrochimica Acta A, 60, 2004, 1873 - 1881.
6) J. M. Forward, J. P. Fackler Jr., Z. Assefa, .Photophysical and Photochemical Properties of Gold(I) Compounds. A Chapter (Chapter 6) In Optoelectronic Properties of Inorganic Systems, Eds. D. M. Roundhill and J. P. Fackler Jr. 195 - 230.
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